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The first bisphosphonic acid‐functionalized benzophenone (BP) and thioxanthone (TX) photoinitiators (PIs), BPBP and TXBP, are synthesized as a new class of water‐soluble PIs for free radical polymerization. BPBP shows excellent solubility (28 g L−1) in water at ambient temperature, compared to TXBP (0.05 g L−1) and also the commercial PI Irgacure 2959 (5 g L−1). BPBP and TXBP show UV–vis absorption...
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