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A new dioxo-molybdenum(VI) complex [MoO 2 (L)(H 2 O)] has been synthesized, using 5-methoxy 2-[(2-hydroxypropylimino)methyl]phenol as tridentate ONO donor Schiff base ligand (H 2 L) and MoO 2 (acac) 2 . The yellow crystals of the compound are used for single-crystal X-ray analysis and measuring Fourier Transform Infrared (FTIR), UV–visible, 1 H NMR and...
The title compound was prepared by reacting mercury(II) cyanide and tetramethylthiourea (Tmtu) in the molar ratio of 1:1.75. It was characterized by IR and NMR (1H and 13C) spectroscopy, and X-ray crystallography. The appearance of a band around 2,200 cm−1 in IR and a resonance around 145 ppm in 13C NMR indicated the binding of cyanide to mercury(II). The crystal structure of the title complex, [{(tetramethylthiourea)...
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