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We report, for the first time, a nanoscale control of the spatial distribution of semiconducting tetrapod (TP) nanocrystals within block copolymer particles. Polystyrene (PS) block copolymer (BCP)/CdSe TP nanocrystal hybrid particles were prepared by the nanoprecipitation of TP/BCP mixtures into methanol. The BCPs consisted of short, polar terminal block bearing methyl disulfide anchoring moiety which...
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