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Polyanion‐type phosphate materials are highly promising cathode candidates for next‐generation batteries due to their excellent structural stability during cycling; however, their poor conductivity has impeded their development. Isostructural and multivalent anion substitution combined with carbon coating is proposed to greatly improve the electrochemical properties of phosphate cathode in sodium‐ion...
In article number 1907645, Xing‐Long Wu and co‐workers propose and develop an advanced strategy (isostructural and multivalent anion substitution strategy) to significantly enhance the electrochemical properties of Na‐super‐ionic conductor‐type phosphate cathode (from Na3V2(PO4)3 to Na3.1V2(PO4)2.9(SiO4)0.1) for sodium‐ion batteries. In addition, theoretical calculation and experimental analyses reveal...
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