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A photoelectrochemical immunosensor was developed for the sensitive detection of microcystin-LR (MC-LR) by using the Au nanoclusters as the substrate and silica-functionalized DNAzyme concatamers as the label carrier. The branched TiO2 nanorods (B-TiO2 NRs) decorated with CdS nanoparticles were modified on FTO and acted as the photoelectrode, while the bioelectrode was prepared by in-situ electrodepositing...
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