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Reaction of [Ru(COD)Cl2]x (COD=1,5-cyclooctadiene) with pyridine-2,6-dicarboxylic acid (dipicH2) in the presence of Et3N afforded an anionic complex [Et3NH][(dipic)(COD)RuCl] (1) with a κ3-dipic coordination mode. Treatment of 1 with AgNO3 in MeOH/H2O afforded a neutral complex [(dipic)(COD)Ru(H2O)] (2) in a high yield. Reaction of 2 with 1equiv. of L gave the according adducts [(dipic)(COD)Ru(L)]...
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