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Two metastable phases have been identified in as-cast Mg-rich Mg–Gd–Zn alloys by TEM characterization. The I-phase was found to have a composition close to Gd11Mg29Zn60 with an icosahedral structure (aR = 0.524 nm). The H2-phase, with a composition close to Gd16Mg14Zn70, was identified to have a hexagonal structure (a = 0.937 nm and c = 0.977 nm). An extension of the thermodynamic description of the...
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