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Chiral Mn(III) salen complexes were supported on mesoporous molecular sieve MCM-48 and employed as catalyst in the asymmetric epoxidation of some unfunctionalized olefins. The as-synthesized catalysts showed excellent enantioselectivity than homogeneous catalysts for α-methylstyrene and the highest ee value (up to >99%) was obtained. Furthermore, these catalysts were also effective for bulkier...
Chiral Mn(III) salen complexes were originally supported on mesoporous molecular sieve MCM-48 and employed as catalyst in the asymmetric epoxidation of some aromatic olefins. The highest ee value(up to >99%) was obtained due to the unique spatial environment constituted by the support.
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