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Ion‐Solvens‐Komplexe fördern die Gasentwicklung von organischen Elektrolyten auf einer Alkalimetallanode. In ihrer Zuschrift auf S. 742 ff. beweisen Q. Zhang et al. dieses Prinzip und validieren seine Anwendbarkeit auf verschiedene Elektrolyt‐Metall‐Systeme. Ein allgemeiner Mechanismus für die Zersetzung von organischen Elektrolyten und die Gasentwicklung wurde entdeckt.
Lithium and sodium metal batteries are considered as promising next‐generation energy storage devices due to their ultrahigh energy densities. The high reactivity of alkali metal toward organic solvents and salts results in side reactions, which further lead to undesirable electrolyte depletion, cell failure, and evolution of flammable gas. Herein, first‐principles calculations and in situ optical...
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