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2,4,6,8‐Tetraazanoradamantane skeleton is a unique rigid cage‐like organic structure that has not been established. In this article, a facile protocol to build all‐bridge‐position‐functionalized 2,4,6,8‐tetraazanoradamantane skeleton by condensation of glyoxal, primary amines and disubstituted malondialdehydes, which were in situ generated from 2,2‐dipropenyl‐1,3‐dioxolane or 4,4‐dimethoxyhepta‐2,5‐diene...
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