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The catalytic effect of iodine on Mukaiyama–Michael reaction has been evaluated experimentally taking three representative silyl enolates, which react effectively with various α,β‐unsaturated ketones in the presence of 10 mol% of iodine giving 1,5‐dicarbonyl products in 74%–87% yield. A study on the mechanism of the iodine catalyzed reaction has been carried out by density functional theory at the...
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