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Die temperaturvermittelte Absorption und Freisetzung von Wasser in Kompositmaterialien, einschließlich einem Metall‐organischen Gerüstmaterial (MIL‐101(Cr)) und einem thermoresponsiven Polymer (Poly(N‐isopropylacrylamid, PNIPAM), wird von G. Maurin, D. Zhao und Mitarbeitern im Forschungsartikel auf S. 11096 demonstriert. PNIPAM wird durch In‐situ‐Polymerisation des Monomers in die Kavität von MIL‐101(Cr)...
We report an in situ polymerization strategy to incorporate a thermo‐responsive polymer, poly(N‐isopropylacrylamide) (PNIPAM), with controlled loadings into the cavity of a mesoporous metal–organic framework (MOF), MIL‐101(Cr). The resulting MOF/polymer composites exhibit an unprecedented temperature‐triggered water capture and release behavior originating from the thermo‐responsive phase transition...
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