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Induction of chirality from an achiral assembly system remains a huge challenge related to the origin of life. Here, induction of chirality in a metal–organic framework (MOF) built from achiral precursors has been realized. Assembling achiral H3BTB ligands and ZnII/CdII clusters leads to a 2D coordination polymer (FJI‐H16), while introduction of achiral pyridine into such assembly system leads to...
Die Einführung von Chiralität in ein Metall‐organisches Gerüst, das aus achiralen Vorläufern durch templatgesteuerte Selbstorganisation aufgebaut wurde, wird auf S. 3124 im Forschungsartikel von Qihui Chen, Maochun Hong et al. aufgezeigt. Die Triebkraft für die Chiralitätserzeugung ist ein templatgetriebener, kinetisch kontrollierter Assemblierungsprozess. Der Prozess der Chiralitätserzeugung wurde...
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