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A remarkable upfield shift of the py α protons of complexed 2,2′-bipyridine in [cis-Pd(bpy)(NO 3 ) 2 ] is observed which is considered to originate from the anisotropic influence of suitably positioned coordinated nitrate anions around the Pd(II) centre of the molecule. A typical complexation-induced downfield shift is observed for the NH 2 protons in [cis-Pd(en)(NO...
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