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Two novel donor–acceptor (D–A) type conjugated polymers using thiophene and hexyl-thiophene spacers between two-dimensional alkyl-thiophene substituted benzo[1,2-b:4,5-b′]dithiophene (BDT-RT) and alkylthieno[3,4-c]pyrrole-4,6-dione (TPD) units are synthesized and characterized. The effects of incorporation of alkyl-thiophene spacers in the polymer backbone on the optical, electrochemical, charge transport...
Two donor–acceptor (D–A) type conjugated polymers using dodecyl- and ethylhexyl-thiophene substituted benzo[1,2-b:4,5-b′]dithiophene (BDT-DDT and BDT-EHT, respectively) as donors and n-alkylthieno[3,4-c]pyrrole-4,6-dione (TPD) as acceptor were synthesized and characterized. The thiophene substituted BDT unit was recognized as a two-dimensional (2D) π-extended segment with high carrier mobility and...
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