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Constructing ambient‐stable, single‐atom‐layered metal‐based materials with atomic precision and understanding their underlying stability mechanisms are challenging. Here, stable single‐atom‐layered nanoclusters of Pd were synthesized and precisely characterized through electrospray ionization mass spectrometry and single‐crystal X‐ray crystallography. A pseudo‐pentalene‐like Pd8 unit was found in...
Nonmetal‐to‐metallo‐aromatic‐ring coordination is reported by Jun Li, Zhikun Wu et al. in their Research Article (e202313491). The unexpected coordination, which is different from the common organo‐aromatic‐ring‐to‐metal coordination, serves single‐atom‐layered Pd nanoclusters with exceptional stability. Furthermore, the dominant horizontal electron transition induces strong optical absorption and...
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