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In article number 2004925, Yan Yu, Yanglong Hou, and co‐workers report a hierarchical porous Na3V2(PO4)2O2F hollow nanosphere material with fast ionic/electronic conductivities, easy and continuous electrolyte supplement and robust electrode integrity properties, kinetically accelerated sodium‐ion storage behavior of high‐capacity, high‐rate and long‐life cycling.
Sodium‐ion batteries (SIBs) are receiving considerable attention as economic candidates for large‐scale energy storage applications. Na3V2(PO4)2O2F (NVPF) is intensively regarded as one of the most promising cathode materials for SIBs, due to its high energy density, fast ionic conduction, and robust Na+‐super‐ionic conductor (NASICON) framework. However, poor rate capability ascribed to the intrinsically...
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