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A series of ternary thermotropic liquid crystalline copolyesters was synthesized through a simple one‐pot melt condensation based on 4‐hydroxybenzoic acid (HBA), 6‐hydroxy‐2‐naphthoic acid (HNA) and 4‐hydroxy‐2‐naphthoic acid (4‐HNA). The structures were modified via the introduction of the asymmetric 4‐HNA unit. High glass transition temperature values (>80°C) and relatively low melting temperature...
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