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Porous carbon plays a significant role in all‐solid‐state lithium‐sulfur batteries (ASSLSBs) to enhance the electronic conductivity of sulfur. However, the conventional porous carbon used in cell with liquid electrolyte exhibits low efficiency in ASSLSBs because the immobile solid electrolyte (SE) cannot reach sulfur confined in the deep pores. The structure and distribution of pores in carbon highly...