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The conformational energy of the 1,3-phenylene bis[4-4′-(methoxy) benzoyloxy] benzoate and 4-chloro-1,3-phenylene bis[4-4′-(methoxy) benzoyloxy] benzoate molecules has been studied using the B3LYP density functional, with a double ζ polarized basis set. These molecules can be seen as a model for the aromatic core of recently discovered banana-shaped mesogens. The relationship between the bent molecular...
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