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A triflic anhydride‐induced annulation of benzoic acids bearing electron‐withdrawing groups with arylalkynes leading to diverse 3‐arylindenones via an unprecedented aryl swapping pathway under an air atmosphere and ball‐milling conditions has been disclosed. Most of the obtained 3‐arylindenones are fluorine‐containing compounds. The present mechanochemical protocol employs easily available and inexpensive...
The serendipitous discovery of dumb‐bell‐shaped C120 under high‐speed vibration milling conditions is described. The mechanochemical protocol has been employed to synthesize the He‐, H2‐ or H2O‐encapsualted C120, the cross‐dimer C130, trimer C180, bridged C60 dimers as well as products from many other reactions of fullerenes, carbon nanotubes and graphenes. Mechanochemistry extended to various reactions...
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