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Wertvolle Produkte aus einfachen Bausteinen: Ein PdII‐Zweikernkomplex überführt Mischungen aus racemischen N‐Benzoyl‐α‐aminosäuren, Nitroolefinen, Acetanhydrid und Manganacetat in biologisch interessante quartäre Aminosuccinimide. Die Produkte werden diastereomerenrein in hoch enantiomerenangereicherter Form gebildet. Schlüsselschritte der Reaktionskaskade sind eine 1,4‐Addition von in situ gebildeten...
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