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Photoimmunotherapy is attractive for cancer treatment due to its spatial controllability and sustained responses. This work presents a ferrocene‐containing Ir(III) photosensitizer (IrFc1) that can bind with transferrin and be transported into triple‐negative breast cancer (TNBC) cells via a transferrin receptor‐mediated pathway. When the ferrocene in IrFc1 is oxidized by reactive oxygen species, its...
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