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Kinetische Einblicke: Der Einfluss des Substituenten in der α‐70‐Seitenkette der MoFe‐Nitrogenase aus Azotobacter vinelandii auf die CO‐Koordination an das aktive Zentrum des Proteins wurde durch Stopped‐Flow‐IR‐Spektroskopie untersucht. Die Messungen ergaben, dass der CO‐Ligand in allen Fällen an die Fe‐2‐3‐6‐7‐Fläche des FeMo‐Cofaktors bindet (siehe Bild).
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