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Several new binuclear and polynuclear dioxomolybdenum(VI) Schiff base complexes have been synthesized. The reaction of bis(acetylacetonato)dioxomolybdenum with 5-dichlorosalicylaldehyde 4-ethylthiosemicarbazide (L1/L2) in the presence of 4,4′-bipyridine (4,4′-bpy) or 4,4′-bipyridine N,N′-dioxide (4,4′-dpdo) gave a binuclear cis-dioxomolybdenum complex [(MoO 2 ) 2 L 2 (D-D)],...
The reactions between bis(acetylacetonato)dioxomolybdenum(VI) and Schiff base ligands derived from 5-chlorosalicylaldehyde or 3-ethoxy-salicylaldehye, and 3-methoxy-benzoic hydrazide (m-anisic hydrazide), 2-furoic hydrazide or 2,4-dihydroxy-benzoic hydrazide in the presence of donor solvents yielded cis-dioxomolybdenum(VI) complexes with the general formula MoO 2 L(D), where L=tridentate Schiff...
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