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Nucleoside analogues with imidazolyl and histidinyl groups were synthesized for site-specific modification on the catalytic core of 10–23 DNAzyme. The distinct position-dependent effect of imidazolyl group was observed. Positive effect at A9 position was always observed. The pH- and Mg 2+ -dependence of the imidazolyl-modified DNAzymes suggested that imidazolyl group in 10–23 DNAzyme probably...
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