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The thermal dissociation of the bisalkoxyamine(denoted StNNSt) releases the styryl St and one of the two isomers of the StNN nitroxide radicals; the former initiates a living chain P and the latter controls the polymerisation by limiting the chain growth. A sequence of dissociation, propagation and recombination reactions produces the StNNP and PNNP bisalkoxyamines as well...
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