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The Fourier-transform infrared reflection absorption spectra (FT-IRAS) are presented for a set of deuterium-labelled ethoxides on Cu(111). Stable ethoxides are formed by deprotonation of the corresponding ethanols on the preoxidized Cu(111) surface. Comparison of the ethoxide vibrational spectra with those of gas phase ethanols and multilayer ethanols on Cu(111) allowed a detailed assignment of...
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