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Adsorption of 2-, 3- and 4-fluorobenzoic acids on an Au(100) electrode in 0.1 M HC1O 4 have been studied using in situ reflection adsorption IR spectroscopy and cyclic voltammetry. It is found that for the fluorobenzoic acids the vertically adsorbed benzoate with both oxygen atoms oriented toward the metal surface is present at positive potentials, and a new adsorbed state due to this vertical...
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