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In this part of the review one of the most famous 10-S-4 sulfurane called Martin sulfurane together with sulfuranes 10-S-5 and persulfuranes 12-S-6 will be presented. Martin sulfurane has been well known for a relatively long time but it is still useful in organic synthesis as a dehydrating, coupling and oxidizing agent. Its use in selected substitution reactions will be also described. Next, synthesis...
The compounds presented herein are sulfuranes 10-S-3 and 10-S-4 containing hypervalent sulfur atom. They have been known for a relatively long time. Nevertheless, they, and especially 10-S-4 species, are still of great interest due to their unique properties. The review presents recent approaches to the synthesis of these compounds, their selected structural, physical, chemical, stereochemical and...
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