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Ultrathin Iron(II) Phthalocyanine (FePc) monolayers have been employed to decouple individual FePc molecules electronically from the metallic substrate, which allows the intrinsic electronic structure of the free molecule to be preserved and imaged by means of low-temperature scanning tunneling microscopy (STM). High-resolution images reveal the standard “cross” structure for molecules adsorbed at...
We report on the structural transitions of molecules on metal surfaces by external electrostatic field. An electrode–molecule–electrode model is considered to quantify the effect of electrostatic forces at the molecule–electrode interface. Within a quasi-parallel-plate capacitor approach, this model reveals how external electrostatic fields change the delicate balance between molecule–substrate and...
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