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In this work one rigid asymmetrical tricarboxylate ligand p-terphenyl-3,4″,5-tricarboxylic acid (H3L) ligand has been synthesized, one unique nano-porous Terbium luminescent metal-organic framework {[Tb(L)(H2O) (DMF)]·DMF}n (1) has been prepared using solvo-thermal techniques. Structural analysis demonstrated that these di-nuclear Tb2O2 clusters are bridged via rigid ter-phenyl backbones of L3− generating...
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