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A new anionic metal-organic framework, {[H3O]2[Zn4(μ4-O)(NSBPDC)4]·16(H2O)]}n (1), was synthesized under solvothermal conditions using a predesigned multifunctional dicarboxylic acid (H2NSBPDC = 6-nitro-2,2′-sulfone-4,4′-dicarboxylic acid). Complex 1 contains 4-connected tetrahedral [Zn4(μ4-O)(CO2)8] clusters, which are further linked by the bridging ligands, generating a threefold interpenetrated...
In this article, two novel three-dimensional (3D) Copper(II)-organic frameworks [Cu(PC)2]n·2DMF(1) and [Cu(PC)2]n·DMF (2) (HPC = 4-(2-(pyridin-4-yl)vinyl)benzoic acid) were obtained from the same reaction mixture but tuned by different solvothermal temperature, The product 1, which was obtained at 160 °C, is a rare fivefold interpenetrating lvt framework, whereas the product 2, obtained at 120 °C,...
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