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A thermodynamic dataset for the Si-C-Al-Y-O system was developed for calculations of heterogeneous phase equilibria and reactions in SiC-base engineering ceramics. The quinary system is of major interest for the understanding of the liquid phase sintering of silicon carbide ceramics using additives like alumina (Al2O3) and yttria (Y2O3). The thermodynamic dataset was developed by the CALPHAD method...
Thermodynamic optimizations of the Mo–Nb, Mo–Ta, and Nb–Ta binary systems were performed by considering the experimental phase diagram and thermodynamic data available from the literature. The Mo–Nb–Ta ternary system was then synthesized from the descriptions of the binary sides. The calculated thermodynamic properties as well as phase diagrams for the binary systems agree well with the experimental...
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