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The molecular structures and relative energies of tetra-, penta-, and hexacoordinated stereoisomers of the bis(ligand) complexes ML2 (M = Ni(II), Zn(II), Cd(II)) with bi- and tridentate heterocyclic azomethine derivatives (coordination modes MN2O2, MN2O2X, or MN2O2X2 (X = S, Se)) are calculated using the density functional theory. The dependences of the relative stabilities of the stereoisomers of...
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