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The reactivity of water with Li‐rich layered Li2RuO3 and partial exchange of Li2O with H2O within the structure is studied under aqueous (electro)chemical conditions. Upon slow delithiation in water over long time periods, micron‐sized Li2RuO3 particles structurally transform from an O3 structure to an O1 structure with a corresponding loss of 1.25 Li ions per formula unit. The O1 stacking of the...
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