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Cubic metal-covalent-supramolecular organic framework (MCSOF-1) hybrid has been created from the reaction of two molecular components and subsequent co-assembly with cucurbit[8]uril (CB[8]) in water. In the presence of CB[8], [Ru(bpy)3]2+ -based acylhydrazine 1·2Cl reacted with aldehyde 2·Cl to quantitatively yield six-armed precursor 3·8Cl through the generation of MCSOF-1. MCSOF-1 combines the structural...
Small Ag clusters confined in the channels of ordered mesoporous anatase TiO2 have been fabricated via a vacuum-assisted wet-impregnation method, utilizing well-ordered mesoporous anatase TiO2 with high thermal stability as the host. The composites have been characterized in detail by X-ray diffraction, X-ray photoelectron spectroscopy, X-ray absorption fine structure (XAFS) spectroscopy, N2 adsorption,...
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