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We present a novel synthesis strategy termed delayed linker addition (DLA) to synthesize hybrid zeolitic‐imidazolate frameworks containing unsubstituted imidazolate linkers (Im) with SOD topology (hereafter termed Im/ZIF‐8). Im linker incorporation can create larger voids and apertures, which are important properties for gas storage and separation. To date, there have been only a handful of reports...
While zeolitic imidazolate framework, ZIF‐8, membranes show impressive propylene/propane separation, their throughput needs to be greatly improved for practical applications. A method is described that drastically reduces the effective thickness of ZIF‐8 membranes, thereby substantially improving their propylene permeance (that is, flux). The new strategy is based on a controlled single‐crystal to...
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