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The mineralization of calcium carbonate (CaCO3) in the solution of amphiphilic block copolymers (ABCPs), polymethylene-b-poly(acrylic acid) (PM-b-PAA), is studied. Uniform vaterite and aragonite were obtained under certain conditions in the presence of PM-b-PAA. The influence of some important variables relating the mineralization including pH, the ABCPs concentration, the ratio of hydrophilic to...
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