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We have prepared new rhodium(I) complexes with two furanoside diphosphines, 3,5,6-trideoxy-3,5-bis-diphenylphosphine-1,2-O-isopropylidene-β-l-idofurano se (1) and 3,5,6-trideoxy-3,5-bis-diphenylphosphine-1,2-O-isopropylidene-α-l-glucofura nose (2), which form six-membered chelate rings when they coordinate to rhodium. NMR spectroscopy of the Rh complexes and molecular mechanics calculations showed...
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