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Zea mays was incubated with the natural phytotoxin benzoxazolin-2(3H)-one (BOA) to investigate the detoxification process. A hitherto unknown detoxification product, 1-(2-hydroxyphenylamino)-1-deoxy-β-gentiobioside 1,2-carbamate (3), was isolated and identified. A reinvestigation of known BOA detoxification products by NMR methods led to the finding that the structure of benzoxazolin-2(3H)-one-N-β-glucoside...
Methanolic extracts of Avena sativa roots previously incubated with the natural phytotoxin benzoxazolin-2(3H)-one contain, in addition to two already described detoxification products, a third one of hitherto unknown structure. The compound has now been identified by NMR and mass spectral methods as 3-β-d-glucopyranosyl-benzoxazolin-2(3H)-one. This structure was confirmed by an independent synthesis...
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