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A new siloxane‐imide‐containing benzoxazine, BZ‐A6, has been successfully synthesized. The thermal properties of the polybenzoxazine (PBZ) prepared from BZ‐A6 (PBZ‐A6) are superior to those of conventional PBZs lacking siloxane groups. The normally brittle PBZs are toughened significantly as a result of adding siloxane‐imide moieties. Moreover, the thermal and UV stabilities of the surface free energy...
A novel siloxane‐imide‐containing polybenzoxazine based on N,N′‐bis(N‐phenyl‐3,4‐dihydro‐2H‐benzo[1,3]oxazine)‐5, 5′‐bis(1,1′,3,3′‐tetramethyldisiloxane‐1,3‐diyl)‐bis(norborane‐2,3‐dicarboximide) (BZ‐A1) was successfully synthesized. The thermal properties of BZ‐A1 are superior to those of conventional polybenzoxazines lacking siloxane groups. Polymerized BZ‐A1 possesses extremely low surface free...
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