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Natürlich: Eine N‐Acyliminium‐Ion‐Cyclisierung nach biologischem Vorbild und eine dynamische rutheniumkatalysierte Cyclocarbonylierung sorgen für die hoch effiziente Synthese von (±)‐Stemoamid. Die silbervermittelte Cyclisierung eines Allenylalkohols könnte sich bei künftigen asymmetrischen Synthesen der Zielverbindung als nützlich erweisen. TMS=Trimethylsilyl.
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