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Neutral and mono-oxidized states of novel sandwich-type tetrakis[2,3,9,10,16,17,23,24-octa(dodecanoyloxy)phthalocyaninato] terbium–cadmium quadruple-decker complex {[Pc(OC12H25)8]Tb[Pc(OC12H25)8]Cd[Pc(OC12H25)8]Tb[Pc(OC12H25)8]} (1) and {[Pc(OC12H25)8]Tb[Pc(OC12H25)8]Cd[Pc(OC12H25)8]Tb[Pc(OC12H25)8]}·SbCl6 (2) were synthesized and spectroscopically characterized. Polarized optical microscope (POM)...
Two new tris(phthalocyaninato) europium complexes Eu2(Pc)[Pc(OPh)8]2 (1) and Eu2[Pc(OPh)8]3 (2) [Pc=unsubstituted phthalocyaninate; Pc(OPh)8=2,3,9,10,16,17,23,24-octaphenoxyphthalocyaninate], were designed and synthesized. Introduction of different number of electron-withdrawing phenoxy substituents at the phthalocyanine periphery within the triple-decker complexes not only ensures their good solubility...
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