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The mononuclear neutral Cr(III) complex, [Cr(L) 3 ] (1) (where LH=4-methyl-2,6-dibenzoylphenol (mdbpH)) has been synthesized and characterized by elemental analysis, conductivity measurement, mass spectrometry, IR, electronic and ESR spectroscopy, cyclic voltammetry and X-ray crystallography. Crystal structure determination reveals that 1 comprises three monoanionic bidentate ligands (2,6-PhCO)...
Several mononuclear copper complexes 1(a–b) and 2(a–b) supported over sterically demanding [NNO] ligands namely, N-(aryl)-2-[(pyridin-2-ylmethyl)amino]acetamide [aryl=2,6-diethylphenyl (1) and mesityl (2)], exhibit catecholase-like activity in performing the aerial oxidation of 3,5-di-t-butylcatehol (3,5-DTBC) to 3,5-di-t-butyl-catequinone (3,5-DTBQ) under ambient conditions. The 1(a–b) and 2(a–b)...
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