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Various reagents such as Cl 2 , Br 2 , I 2 , benzoyl peroxide and CH 3 I add to the dinuclear gold(I) amidinate complex [Au 2 (2,6-Me 2 Ph-form) 2 ] to form oxidative-addition gold(II) metal–metal bonded complexes. The gold–gold distance in the dinuclear complex decreases upon oxidative-addition with halogens from 2.7 to 2.5Å, similar to observations...
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