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Ein “Clusterlinker”‐Ansatz wurde für den Aufbau von Cluster‐basierten Metall‐organischen Gerüsten entwickelt, wie Q.‐M. Wang et al. in der Zuschrift auf S. 12985 ff. berichten. Die Lumineszenz des Clusters wurde damit in das difunktionelle poröse Gerüst eingeführt, das NbO‐Topologie besitzt. Das so gebildete lumineszierende poröse Material zeichnet sich durch stärkere Emission und solvatochromes Verhalten...
A cluster‐based luminescent porous metal–organic framework has been constructed through a “cluster linker” approach. The luminescent gold(I) cluster, prefunctionalized with pyrazinyl groups, was used as a cluster linker, similar to an organic linker, to connect silver ions in order to form a 3D framework. 1D channels with 1.1 nm diameter were observed in the framework. The cluster with its intrinsic...
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