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The bulk properties and structural characteristics of emulsions arise substantially from their interfacial rheology, which depends strongly on surfactant mass transfer and its coupling to flow. Typical methods used to measure such properties often employ simpler flows and larger drops than those encountered in typical processing applications. Mass transfer mechanisms are governed by droplet size;...
A new strategy to reduce the volume shrinkage of photo‐cross‐linking polymeric materials using an in situ nanocavitation process has been developed. A small amount of the cavitation agent introduced to a model system effectively reduces volume shrinkage upon photopolymerization to essentially zero. The method shows promise for electronic, coating, and dental applications.
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