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The optimal synthesis temperature of BiFeO3 is found. The cube BiFeO3 powders have a hexagonal perovskite structure with a space group R3c, while the sphere-like BiFeO3 powders have a rhombohedral structure with a space group R3m. The growth mechanism of crystallization–dissolution–crystallization has been summarized and verified. The effect of the reaction time on the particle size in hydrothermal...
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