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Reactivity of halide anion (Cl−) with monolayer-protected gold nanoclusters (MPCs) of 1.8 nm in diameter has been studied. Typically, thin films of MPCs were prepared on an electrode surface and immersed in aqueous solutions containing Cl−. It was observed that Cl− inevitably resulted in the destruction of electrochemical charging of MPC films, which was studied and analyzed in details by cyclic voltammetry,...
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